Each of the various processes of gas manufacturing used feedstock materials to
create gas, first for purposes of illumination and later (generally after 1890)
for heat and fuel. In order to generate and capture the gas released from the
feedstock, organic matter of some type was sealed in retorts, ovens or generator
set shells (names depending on the process) and heated in the absence (pyrolytically)
of oxygen. This roasting drove off the volatile content of the feedstock, as
gas, which was captured and cleansed of impurities so that it would serve the
consumer for the intended purpose (light, heat or fuel energy).
There is a hierarchy of product and residual involved in gas manufacture. In
most cases gas was manufactured with itself as the desired product, and the
other forms of liquids and solids produced in the process were considered
residuals and waste. At the first instant, the two of the residuals were
recognized as by-products of value (coke) or potential value (tar) and the
ammoniacal liquor considered largely as a waste. By about 1820 forms of tar
distillation were underway as water sealant-repellent, and ammonia was being
concentrated as a cleansing fluid. In the 1850s initial discoveries were made
(Britain) of the dye
qualities available from oil (tar) fractions separated to the individual
compound level and the world chemical industry was launched on the basis of coal
tar as its feedstock.
Sources of
Residual By-products and Waste
|
|
Component |
MGP Use |
Waste Source Location
& Potential |
|
Transportation Spur |
Delivery point of feedstocks;
exit point of salable residuals |
Human labor was a significant cost to gas making. Feedstocks were brought as
close as possible to the retorts and generator houses. |
|
Coal Yard |
Storage area which kept coal dry for optimal use in firing boilers or as
retort feedstock |
Kept as close as feasible to the retorts and generators. Many plants
chose to place coal in sheds so as to optimize gasification in the presence
of minimal water content. |
|
Coke Yard |
By-product coke from coal-gas plants |
Used symbiotically as feedstock for various water gas plants, especially as
co-located |
|
Retort House |
Coal-gas retorts housed internally in benches; groups of benches
known as
stacks |
The central building of the gas-making process; generally located at the
corner of the plant with highest elevation and near the gate, from which the
processed gas left the plant through the station meter. Origin of coke
quench water = ammoniacal liquor. |
|
Generator House |
Location of generator sets for carburetted water gas and
oil-gas processes |
Generation capacity such that vastly smaller space required for commensurate
production over that required for coal-gas process |
|
Condenser House |
Building or addition immediately adjacent to retort house or generator house |
After 1910, tended to be out-of-doors. Same configuration used for all gas
generating processes; a wet process that concentrated and/or precipitated
tars for further management. |
|
Scrubber |
Tall (5-10 m) right-circular cylinders with slanted trays holding
contaminant-absorbing wood
fiber/chips |
Usually employed a water shower to remove tar and other process residuals
from the gas. Residuals captured in scrubber sump for further
management. |
|
Washer |
Gas immersed in agitated water bath to cool gas and drop tar particles into
its sump. |
With carburetted water gas and enhanced oil-gas. When designed as a
water-seal/wash box, placed first in the
clarification sequence as a seal against back-flow of gas. |
|
Combined Washer- Scrubber |
When employed, generally post-1895 |
Enhanced the recovery of tar from gas. Trapped tar held on sorbant and
in sump. |
|
Sumps of Clarification Devices |
Condensers, scrubbers and washers, and their combinations had bottom sumps
to trap and yield tar and tar sludges |
Tar generally removed manually for recovery, reuse or dumping.
Spills and leaks assumed in a generic sense.
Tar sludges contained refractory geologic impurities such as quartz and
feldspar, entering the system mainly from feedstocks. |
|
Exhauster |
Steam-driven gas evacuator employed to reduce gas pressure and promote flow through
system |
Position of exhauster chosen by the plant gas engineer to achieve optimal
flow of gas through the tar-removal clarification process; most plants had a
backup exhauster in parallel. |
|
Purifiers
(Purifier Boxes) |
Gas was passed through “boxes” containing layers of lime, wood chips, oxide
of iron (particles) and/or
strips of iron as various forms of sorbants, often in conjunction with each
other.
Generally employed minimally as a pair of “boxes” in series, with at least
a spare pair in parallel. |
Trapped some tar, but designed to trap sulfur, cyanide, arsenic and other
heavy metals all of which originated in or from the organic gas feedstock
materials |
|
Relief Holder
|
1) With coal gas, the oldest of the gas holders, serving as a raw-gas
exposure to tar-dropping seal water before clarification/purification.
2) With carburetted or oil-enhanced water gas a usually necessary (*) presence to buffer
gas-pressure variations on blow-run cycles.
* Under some circumstances it was possible for small CWG plants to
operate without a relief holder. |
Relief holders of the first variety can be expected to have subsurface
"tanks" (pits = basins) commonly abandoned and virtually full of unrecovered tar.
Second variety holder tanks tend to be less commonly abandoned with large
volumes of water-gas tar, unless dumped at time of plant decommissioning. |
|
Gas
Holders
(Gasometers) |
As many as needed; ever more and larger as the gas business expanded.
Generally predicated on the largest holder being equivalent to one day’s make.
Of prime concern are the subsurface tanks most common to pre-1900 varieties. |
Of several basic design variations.
Those pre-1900 have a subsurface water-seal tank likely to have leaked
considerable amounts of precipitated and trapped PAHs to the subsurface
soil, rock and groundwater,0 through various fractures
related to brick, masonry and/or concrete or composite construction
materials. Valve pits commonly exhibit hot-spot concentrations of PAH
contamination |
|
Tar
Wells and Tar Cisterns |
Subsurface tanks,
right-circular cylinders and rectangular or square-sided; brick, masonry or
concrete or composite.
Less commonly known
as “ammonia wells”. |
Commonly designed with a self-functioning gas-liquor (process water)
discharge system to carry off lightest-fraction of gas liquor while
retaining the gravity-separated tar fraction; all subject to
through-fracture flow leakage to the surrounding earth during the
operational period. |
|
Tar Extractor |
Typically an above-ground mechanical device for separating tar particles
from the passing gas. |
Most common and best known were the "P & E" devices of French manufacture. |
|
Tar Separator |
Both as above-ground
devices housed in structures and as subsurface rectangular-form
concrete or wood “tanks,” the latter often made of wood planks subject to
between-plank leakage. |
Above-ground devices were machines built to physically separate tar
particles from gas liquor; below-ground devices contained flow baffles
functioning to slow in-out flow of gas liquor carrying suspended tar, the
latter dropped to the sump of the tar separator. |
|
Boiler House |
Necessary to power
the extractor and a variety of small steam engines and fluid pumps |
Generally consumed coal or by-product coke; could be rigged for burning tar,
under close supervision of temperatures. Ash not expected to be toxic unless
later so exposed. |
|
Oil Storage Tanks
(Above Ground and Underground) |
Illuminating or
enriching oil for non-coal-gas production |
Generally petroleum oils susceptible to biodegradation if leaked or spilled;
generally no incentive or rationale to dump |
|
Plant Plumbing |
Below-ground piping,
often in trenches or pipe chases. |
Virtually all process piping was subject to corrosion and release of PAHs,
or release through joints and seams. Well known to the gas industry
since 1860s. |
|
Yard Drips
(Drip Pots) |
Light-oil (drip oil)
collection sumps placed along gas-flow pipes in the gas yard. |
Used to collect naphthalene and other light oils; these were of value and
were recycled, usually as carburettion oils for water gas, or as industrial
solvents. Sometimes disposed of as herbicide or by dumping. |
|
Furnaces |
The fire box located
below gas benches and all boilers. |
Source of operational heat; residue was only ash, cinder, clinker or slag;
not expected to be hazardous by nature of its formation. |
|
Station Meter |
Plant production
measuring device housed in a building at the gas-outlet from the plant. |
Generally co-located with the plant office and in the up-gradient end of the
site, near the plant gate. Not a source of contamination. |
|
Governor |
Gas flow control
device adjusting distributed gas to main distribution pressure. |
Should not be a source of contamination. |
|
Rail-Spur Spills |
Operational-era
spills of tars and other fluid residuals (light oils and ammonia) being
transferred off-site as by-products. |
Naturally most prominent at larger plants and those plants engaged in
by-product recovery operations. |
|
Purification Box Media Spreading Ground |
Wood-chip and some
forms of iron oxide media could be
revivified
on this pad and returned for re-use short of ultimate “spent” condition |
Action implies shaking and mass-expansion via pitch forks. Sulfur and
Prussian blue (cyanide) could be raked up and sold as by-products in many
instances. |
|
Spent Wood-Chip Box Waste Burning Ground |
A corner or side area
of the gas yard where dry chips could be torched and destroyed by fire. |
Required dry climate or dry season; ashes carried to a plant dump. |
|
Plant Dump |
Primary disposal site
on the gas yard; broken, fractured, slagged retort bricks; generator lining
bricks, all manner of scurf or other carbon-slag wastes, ash, clinker, slag,
off-specification tar, tar sludge, lampblack, box wastes, bottles, purifier
shelf slats, broken window glass, corroded pipe, scrap iron, wagon and vehicle
parts, and broken gas-plant equipment. |
Expect a toxic character in general. Plant dump likely will be found in or
at the furthest down-slope corner or extension of the gas yard, along the
adjacent creek, stream, or river, or filling any original topographic
declivity of the ground at the site. In almost all cases, the plant
dump was filled early and supplemented with multiple dumps around the
periphery of the gas plant, to within a several-block wagon haul distance. |